SunNIght Solar, makers of a significant solar powered flashlight, is offering a "Buy One, Give One" ("BOGO") program, where for about 25% more, you can send a flashlight to the developing world. This seems like a model that would work well across many products of interest to developing countries (medicines, vaccines...) -- particularly if organized on a "bogo.org" web site that publicized opportunities, tracks purchases, audits delivery, and provides tax deductions.
http://www.bogolight.com